


Exposure to Heat
The decomplace of hydrogen peroxide is exothermic and also also the price of decomposition increases via increasing temperature. If the heat of decomposition is not rerelocated at the rate at which it is arisen (by warm loss to the surroundings or cooling), the temperature will certainly rise and also the rate of decomposition will certainly rise. This event deserve to bring about a self-accelerating decomposition which, in the instance of badly contaminated options, may finish in incredibly rapid decomposition or “boil off”.
Venting and also Circulation
For services approximately 64% concentration liquid water is still present, even after the total decomposition. As such, the final decomplace temperature cannot exceed the boiling allude of water. For services higher than 64% concentration, enough heat is created to evaporate all of the water. Super-heated solution has actually potential to reason container rupture. Example, 70% hydrogen peroxide can reach a temperature of 240°C (513 K). One volume of 70% solution, when completely decomposed under adiabatic conditions and atmospheric push, will produce around 2,500 volumes of gas compared to the original volume.You are watching: Why is hydrogen peroxide stored in a dark bottle
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Storage Container Materials
